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Over Potential and Electrolytic Cells?

For Aqueous NaCl electrolytic cells, you can have either chlorine as the anode or h20– how do you choose which one? When comparing overpotentials, do you choose the one with the bigger over potential or the smaller one and why? Please help, I would really appreciate it!

are secondary cells galvanic cells or are they electrolytic cells?

im abit confused when they ask about secondary cells in yr 12 chem bcos i have to know if its a galvanic cell or electrolytic cell so that i can determine the charges and which electrodes are the cathode and anode if you can answer this for me.. ill be very appreciative =DD thankyou

Electrolytic Cells?

Commercial electrolytic cells for producing aluminum operate at 5 volts and 100,000 Amperes. How long does it take to produce 1000 kilograms of aluminum? a. 1 x 10^15 seconds b. 9 x 10^6 seconds c. 7 x 10^3 seconds d. 3.3 x 10^4 seconds e. 1 x 10^5 seconds