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  1. The “overvoltage” of a cell is the voltage (potential) in excess of the standard potential needed to make current flow in the cell.

    I.e.
    standard cell potential for a hypothetical cell a 0 current = 1.23 V
    potential needed to get current to flow = 1.50 V
    the overvoltage is 0.28 V

Electrolytic Cells and “Over Voltage”?

Can someone explain this concept to me, please? I would really appreciate it!